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Kinetics of the First Order Autocatalytic Decomposition Reaction of Nitrocellulose (13.86% N)
Author(s) -
Guo PengJiang,
Hu RongZu,
Ning BinKe,
Yang ZhengQuan,
Song JiRong,
Shi QiZhen,
Lu GuiE,
Jiang JinYou
Publication year - 2004
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20040220106
Subject(s) - autocatalysis , chemistry , nitrocellulose , kinetics , decomposition , autocatalytic reaction , order of reaction , first order , chemical decomposition , degree (music) , thermal decomposition , thermodynamics , reaction rate constant , organic chemistry , catalysis , statistical physics , classical mechanics , mathematics , biochemistry , physics , membrane , acoustics
The kinetics of the first order autocatalytic decomposition reaction of nitrocellulose (NC, 13.86% N) was studied by using DSC. The results show that the DSC curve for the initial 508 of conversion degree of NC can be described by the first order autocatalytic equationand that for the latter 50% conversion degree of NC described by the reaction equations.