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Heck reaction of iodoarenes with methyl acrylate catalyzed by cyclopalladated complexes of tertiary arylamines immobilized in ionic liquid [Bmim] + BF 4 −
Author(s) -
Zheng Rui,
Yang Fan,
Zou Gang,
Tang Jie,
He MingYuan
Publication year - 2003
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20030210902
Subject(s) - chemistry , ionic liquid , tetrafluoroborate , catalysis , methyl acrylate , heck reaction , acrylate , polymer chemistry , medicinal chemistry , organic chemistry , palladium , polymer , copolymer
Abstract Heck reaction of iodoarenes with methyl acrylate, catalyzed by cyclopalladated complexes of tertiary arylamines, was investigated in ionic liquid 1‐butyl‐3‐methy Imidazolium tetrafluoroborate ([Bmim] + BF 4 − ). The products can be isolated conveniently from the ionic liquid‐catalyst system. The catalysts could be reused for more than 10 times still with satisfactory catalytic activity.