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Enhancive Synthesis of ‐lβ, 11‐Diol‐4‐en‐eudesmol
Author(s) -
Chen JinChun,
Zheng GuoJun,
Zhang Chen,
Fang LiJing,
Li YuLin
Publication year - 2003
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20030210736
Subject(s) - chemistry , diol , cationic polymerization , diene , diels–alder reaction , organic chemistry , catalysis , natural rubber
Abstract An enhancive synthesis of −1β, 11‐diol‐4‐en‐eudesmol, starting from 2‐chloroacrylonitrile, is described. The effect of temperature on the Diels‐Alder reaction of 2‐chloroacrylonitrile with 2‐methylfuran and the condition of cationic cyclization of diene were discussed in detail.