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Catalytic Asymmetric [2, 3]‐Sigmatropic Rearrangement of Sulfur Ylides Generated from Carbenoids and Allenic 2‐Methylphenyl Sulfide
Author(s) -
Zhang XiaoMei,
Ma Ming,
Wang JianBo
Publication year - 2003
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20030210732
Subject(s) - chemistry , sigmatropic reaction , sulfur , sulfide , catalysis , carbonyl sulfide , ylide , enantioselective synthesis , medicinal chemistry , organic chemistry
The first investigation on catalytic asymmetric [2, 3]‐sigmatropic rearrangement of sulfur ylides generated from carbenoids and allenic phenyl sulfide was carried out. Up to 55% ee value was obtained.
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