Mercaptolysis of the E/F Rings of Steroidal Sapogenins: A Concise Synthesis of Δ 20(22) ‐Furostene‐26‐thioethers | Zendy

Tian WeiSheng | Zendy; Guan HuiPing | Zendy; Pan XinFu | Zendy

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Mercaptolysis of the E/F Rings of Steroidal Sapogenins: A Concise Synthesis of Δ 20(22) ‐Furostene‐26‐thioethers

Author(s) -

Tian WeiSheng,

Guan HuiPing,

Pan XinFu

Publication year - 2003

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.20030210714

Subject(s) - sapogenin , chemistry , molecule , steroid , lewis acids and bases , stereochemistry , organic chemistry , catalysis , biochemistry , hormone , medicine , alternative medicine , pathology

Lewis acid catalyzed mercaptolysis of steroidal sapogenins was reinvestigated. Besides obtaining the reported 26‐thioacetals 5 under milder conditions, a new type of compounds Δ 20(22) ‐furostene‐26‐thioethers 6 were also synthesized through the mercaptolysis of steroidal sapogenins, which can be used to the synthesis of the steroidal molecule with side chains.

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