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Stereoselective Synthesis of ( E )‐ and (Z)‐1,2‐Disubstituted Ethene from Polymer‐Supported Vinylic Selenide
Author(s) -
ShouRi Sheng,
Xian Huang
Publication year - 2003
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20030210423
Subject(s) - chemistry , stereoselectivity , selenide , reagent , catalysis , coupling reaction , combinatorial chemistry , polymer , organic chemistry , grignard reagent , medicinal chemistry , stereochemistry , selenium
This letter describes a method for the stereoselective synthesis of polymer‐supported vinylic selenides and their applications to synthesis of ( E )‐ and (Z)‐1,2‐disubstituted ethenes on solid‐phase by the coupling reaction with Grignard reagents under the catalysis of NiCl 2 (PPh 3 ) 2 .
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