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Solvothermal Synthesis and Crystal Structure of a Novel Inorganic‐Organic Hybrid Material, Fe 2 O(OH)(C 5 H 4 NCOO)SO 4
Author(s) -
HongYou Guo,
ZengHe Li,
XiuYan Li,
ChangYuan Zhang,
RuJi Wang
Publication year - 2003
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20030210422
Subject(s) - chemistry , monoclinic crystal system , solvothermal synthesis , aqueous solution , crystal structure , crystallography , hybrid material , inorganic chemistry , nuclear chemistry , organic chemistry
A novel inorganic‐organic hybrid material, Fe 2 O(OH)(C 5 H 4 ‐NCOO)SO 4 was synthesized via solvothermal route using a reaction of FeCl 3 ·6H 2 O, KCNS, and 4‐cyanopyridne in aqueous solution of H 2 O 2 and ethanol at 130 °C for 3 d. The compound crystallized in monoclinic space group P 2 1 , with cell parameters a =0.73850(15) nm, b = 0.65100(13) mn, c = 1.0546(2) nm, β = 90.36(3)°, V = 0.50700(18) nm 3 and Z = 2. The structure is constructed with inorganic layered [Fe 2 O(OH) SO 4 ] + cations linked by organic (C 5 H 4 NCOO) − anions. The compound is thermally stable up to approximately 240 °C.