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Investigation of Copper Halide: Hydrothermal Syntheses and Characterization of CuBr 2 (C 12 H 8 N 2 ) and Cu 3 Br 3 (C 12 H 8 N 2 ) 2
Author(s) -
XiaoLi Zhao,
JiQing Xu,
LiJuan Zhang,
JieHui Yu,
QingXin Zeng,
XiaoBing Cui,
TieGang Wang,
TianWei Wang
Publication year - 2003
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20030210316
Subject(s) - monoclinic crystal system , chemistry , crystallography , halide , magnetic susceptibility , thermogravimetric analysis , crystal structure , copper , hydrothermal synthesis , single crystal , hydrothermal circulation , x ray crystallography , diffraction , inorganic chemistry , organic chemistry , seismology , geology , physics , optics
The reaction of CuBr 2 with 1,10‐phen‐H 2 O (1,10‐phen = 1,10‐phenanthroline) gave two compounds: CuBr 2 (C 12 H 8 N 2 ) and Cu 3 Br 3 (C 12 H 8 N 2 ) 2 . Their structures have been characterized by single‐crystal X‐ray diffraction analysis, elemental analyses, thermogravimetric analyses (TGA) and measurement of variable temperature magnetic susceptibility. Crystal data for CuBr 2 (C 12 ‐H 8 N 2 ): monoclinic, space group P 2 1 / n, a = 0.9977(3) nm, b = 0.65138(14) nm, c = 1.8207(4) nm, β = 91.624(18)°, V = 1.1828(5) nm 3 , Z = 2. Crystal data for Cu 3 Br 3 (C 12 H 8 N 2 ) 2 : monoclinic, space group C2/c, a = 1.00167(11) nm, b = 1.4523(4) nm, c = 1.6295(3) nm, β = 94.386(14)°, V = 2.3635(8) nm 3 , Z = 3.
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