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X‐Ray Structure of 8‐Quinolinolato Lanthanide Complex: (8‐Quinolinolato) bis (2,6‐di‐ tert ‐butyl‐4‐methylphenoxo) samarium
Author(s) -
Yuan FuGen,
Liu QmgSheng,
Weng LinHong
Publication year - 2002
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20020201227
Subject(s) - samarium , chemistry , lanthanide , dimer , elemental analysis , crystallography , inorganic chemistry , organic chemistry , ion
The heteroleptic (8‐quinolinolato)bis(2,6‐di‐ tert ‐butyl‐4‐methyl‐phenoxo) samarium complex was synthesized and characterized by elemental analysis, IR spectrum and X‐ray diffraction analysis. The complex is a five‐coordinate dimer. Each 8‐quinolinolato oxygen atom links two samarium atoms as a bridge and the Sm‐N bond is a typical donor bond.