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Chemoselective Benzylation and Allylation of 4‐Nitrobenzaldehyde Promoted by Phase Transfer Catalyst and Metal in Aqueous Media
Author(s) -
Zha ZhengGen,
Xde Zhen,
Zhou CunLiu,
Wang ZhiYong,
Wang YuSong
Publication year - 2002
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20020201204
Subject(s) - chemistry , catalysis , halide , phase transfer catalyst , aqueous medium , phase (matter) , metal , aqueous solution , organic chemistry , combinatorial chemistry
The benzylation and allylation of 4‐nitrobenzaldehyde (1) could be controlled chemoselectively by using different phase transfer catalyst (FTC) and different metal catalysts. And then, benzylation and allylation of 1 with various organic halides has been realized in high yields in aqueous media.