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Aerobic Oxidation of Methyl Vinyl Ketone in Supercritical Carbon Dioxide
Author(s) -
Ouyang XiaoYue,
Jiang HuanFeng,
Cheng JinSheng,
Zhang QunJian
Publication year - 2002
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20020201128
Subject(s) - chemistry , carbon dioxide , supercritical carbon dioxide , methyl vinyl ketone , ketone , acetal , oxygen , supercritical fluid , selectivity , organic chemistry , catalysis
Aerobic oxidation of methyl vinyl ketone to acetal in supercritical carbon dioxide are achieved in high conversion and high selectivity when oxygen pressure reaches to 0.5 MPa. The effects of cocatalysts, additive, pressure and temperature of the reaction are studied in detail.