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Synthesis and Characterization of a Series of New Functional Poly(ferrocenylenesilanes) for Nonlinear Optics
Author(s) -
Liu YunYang,
Zhang Xuan,
Tang HongDing,
Wang TingJuan,
Qin JinGui,
Liu DaoYu,
Li ShaoJnn,
Ye Cheng
Publication year - 2002
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20020201111
Subject(s) - chemistry , polymer , chromophore , carbazole , differential scanning calorimetry , nonlinear optics , characterization (materials science) , second harmonic generation , polymer chemistry , gel permeation chromatography , analytical chemistry (journal) , chemical engineering , photochemistry , nonlinear system , organic chemistry , nanotechnology , optics , materials science , laser , physics , engineering , quantum mechanics , thermodynamics
A series of new poly (ferrocenylenesilanes) containing carbazole as charge transporting agent and Dispersed Red 1 (DR‐1) as second‐order nonlinear optical (NLO) chromophore was synthesized. The resulting polymers represent the first example of NLO polymer with ferrocenyl groups in the backbone. This series of polymers was characterized with 1 H NMR, LTV‐vis, IR spectroscopies, differential scanning calorimeter (DSC) and gel permeation chromatography (GPC). A preliminary measurement on NLO property of the polymers was carried out with in‐situ second‐harmonic generation (SHG) measurement.