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One‐Dimensional Network Constructed by Salicylate and Phenanthroline Ligands with Copper (II)
Author(s) -
Zhu LagGuan,
Cai GuoQiang
Publication year - 2002
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20020201013
Subject(s) - chemistry , chelation , carboxylate , copper , bridging (networking) , stereochemistry , phenanthroline , ion , polymer chemistry , inorganic chemistry , organic chemistry , computer network , computer science
A novel complex, [Cu 2 (phen) (sal) (Hsal) 2 ] n (1), was synthesized and structurally characterized. The base dimeric units are hold by sal ligands and extended into 1‐D network. The carboxylate groups of salicylates coordinate to the central ion in three different coordination modes: chelating, bridging and bridging‐chelating. In the case of bridging‐chelating of the carboxylate group of the salicylate, all three oxygen atoms of salicylate are bidentately coordinated to copper ion, namely, μ 4 ‐η 3 binding mode.