Premium
Synthesis, Characterization and Crystal Structure of Chlorodibenzyltin (IV) Complex with Dithiomorpholinocarbamate Ligand
Author(s) -
Yin HanDong,
Wang ChuanHua,
Ma ChunLin,
Wang Yong
Publication year - 2002
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20020200922
Subject(s) - chemistry , triclinic crystal system , crystallography , crystal structure , ligand (biochemistry) , molecule , stoichiometry , crystal (programming language) , atom (system on chip) , x ray crystallography , stereochemistry , diffraction , biochemistry , physics , receptor , organic chemistry , optics , computer science , programming language , embedded system
Chlorodibenzyltin (IV) complex with dithiomorpholinocarbamate ligand was synthesized by the reaction of dibenzyltin dichloride with dithiomorpholinocarbamate in 1:1 stoichiometry. The complex was characterized by elementary analysis, UV, BR and 1 H NMR spectra. The crystal structure was determined by X‐ray single crystal diffraction study. The crystallographic data are as follows: triclinic, space group P 1 , a = 0.8723 (2) ran, b = 1.099 (2) nm, c = 1.1036 (3) nm, α = 86.498 (4)°, β = 89.697 (5)°, γ = 82.807 (5)°, Z = 2, V = 1.0479 (4) nm 3 , D c = 1.580 g/cm −3 , μ = 1.553 mm −1 , F (000) = 500, R 1 = 0.0442, wR 2 = 0.0974. The crystal consists of discrete molecules containing five‐coordinate tin atoms in a distorted tigonal bipyramidal configuration. The molecules are packed in the unit cell in one‐dimensional chain structure through a weak interaction between the chlorine atom and sulfur atom, the sulfur atom and one of the sulfurs of an adjacent molecule.