Study on the Phase Diagram of CsCl‐CeCl 3 ‐HCl (11%)‐H 2 O System and the Properties of the Compounds | Zendy

Wang Hui | Zendy; Duan JinXia | Zendy; Ran XinQuan | Zendy; Gao ShiYang | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Study on the Phase Diagram of CsCl‐CeCl 3 ‐HCl (11%)‐H 2 O System and the Properties of the Compounds

Author(s) -

Wang Hui,

Duan JinXia,

Ran XinQuan,

Gao ShiYang

Publication year - 2002

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.20020200920

Subject(s) - chemistry , luminescence , photon upconversion , phase diagram , fluorescence , analytical chemistry (journal) , fluorescence spectroscopy , solubility , phase (matter) , spectroscopy , infrared , ion , chromatography , optics , organic chemistry , physics , quantum mechanics

The equilibrium solubility of CsCl‐CeCl 3 ‐HCl (11%)‐H 2 O quaternary system at 25 °C has been determined by the physic‐chemical analysis method, and the phase diagram was plotted. Two new double salts 3CsCl · CeCl 3 · 3H 2 O and CsCl · CeCl 3 · 4H 2 O obtained from the complicated system were identified and characterized by XRD, TG‐DTA, DSC, UV and fluorescence spectroscopy. Studies on the fluorescence excitation and emission show that 3CsCl · CeCl 3 · 3H 2 O and CsCl · CeCl 3 · 4H 2 O have upconversion luminescence of infrared‐visible range, and the upconversion emission intensity increases with the increase of ratio of CeCl 3 in CsCl.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research