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Hydrothermal Syntheses, Supramolecular Structures and the Third‐order Non‐linear Optical Properties of Three Copper (I) Halide Amine Complexes Connected via Secondary Bonding Interactions
Author(s) -
Yu JieHui,
Xu JiQing,
Han Li,
Wang TieGang,
Shi Zhan,
Jing WeiJie,
Ding Hong,
Xu JiaNing,
Jia HongBin,
Hua Jia
Publication year - 2002
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20020200910
Subject(s) - chemistry , supramolecular chemistry , halide , copper , ethylenediamine , hydrogen bond , crystallography , amine gas treating , denticity , hydrothermal circulation , absorption spectroscopy , crystal structure , inorganic chemistry , molecule , organic chemistry , chemical engineering , physics , quantum mechanics , engineering
The hydrothermal reactions of Cul, KI and bidentate amines [1, 10‐phenanthroline (phen) or ethylenediamine (en)] gave the three copper (I) halide compounds, Cu 3 I 3 (phen) 2 (1), CuI (phen) 2 (2) and [Cu (en) 2 ] [CuI 2 ] 2 (3), which were structurally characterized via single‐crystal X‐ray diffraction studies. Hydrogen bonds and τ‐τ interactions are the most remarkable structural features of the title compounds. All can be described as higher‐dimensional supramolecular compounds connected via these secondary bondings. Moreover, the title compounds were characterized by elemental analyses, IR spectra and TGA analyses. The third‐order non‐linear optical properties of the title compounds were also investigated and all exhibit nicer non‐linear absorption and self‐focusing performance.