Synthesis and Crystal Structure of a One‐Dimensional Coordination Polymer Containing Unusual Na 2 Cu 2  Tetrametallacyclic Units | Zendy

Gao EnQirjg | Zendy; Sun HaiYing | Zendy; Liao DaiZheng | Zendy; Jiang ZongHui | Zendy; ShiPing Yan | Zendy

Premium

Synthesis and Crystal Structure of a One‐Dimensional Coordination Polymer Containing Unusual Na 2 Cu 2 Tetrametallacyclic Units

Author(s) -

Gao EnQirjg,

Sun HaiYing,

Liao DaiZheng,

Jiang ZongHui,

ShiPing Yan

Publication year - 2002

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.20020200811

Subject(s) - chemistry , perchlorate , supramolecular chemistry , sodium perchlorate , crystallography , ion , coordination polymer , crystal structure , stereochemistry , chelation , sodium , inorganic chemistry , electrochemistry , organic chemistry , electrode

A unique coordination polymer, {[CuLNa(ClO 4 )]·H 2 O} n (1), was isolated from the solution containing sodium perchlorate and the neutral macrocyclic oxamidocopper(II) complex [CuL] (H 2 L = 2,3‐dioxo‐5,6:13, 14‐dibenzo‐7, 12‐bis(ethoxycarbonyl)‐1, 4, 8, 11‐tetraazacyclotetradeca‐7, 11‐diene). The complex is composed of [Na 2 Cu 2 ] tetrametallacycles bridged by perchlorate ions to form infinite one‐dimensional chains which are stacked via τ‐τ interactions and weak coordination bonds to result in a two‐dimensional supramolecular network. The perclorate ions were found to coordinate to sodium atoms in the unusual bridging chelating tridentate mode of μ 2 ‐(O:O′,O″).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research