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Dramatic Solvent Effect in the Reduction of 2,3‐Allenoic Acid Esters. A Simple Synthesis of 2,3‐Allenols from 2,3‐Allenoates
Author(s) -
Yin ShaoHu,
Ma ShengMing,
Jiao Ning,
Tao FengGang
Publication year - 2002
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20020200717
Subject(s) - chemistry , solvent , toluene , reduction (mathematics) , hydride , simple (philosophy) , organic chemistry , hydrogen , philosophy , geometry , mathematics , epistemology
2,3‐Allenols were prepared conveniently from the reduction reaction of 2, 3‐allenoates with DIBAL‐H (Diisobutylaluminum hydride) in toluene. A dramatic solvent effect was observed for this reaction.