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Hydrothermal Synthesis and Characterization of a One‐Dimensional Copper (I) Halide Cluster with 1,10‐Phenanthroline
Author(s) -
Yu JieHui,
Shi Zhan,
Xu JiQing,
Cui XiaoBing,
Ding Hong,
Jing WeiJie,
Chu DeQing,
Hua Jia,
Xu JiaNing,
Wang TieGang
Publication year - 2002
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20020200608
Subject(s) - chemistry , monoclinic crystal system , crystallography , copper , halide , phenanthroline , crystal structure , zigzag , hydrothermal synthesis , covalent bond , cluster (spacecraft) , ion , hydrothermal circulation , stereochemistry , inorganic chemistry , geometry , programming language , mathematics , organic chemistry , seismology , computer science , geology
The title compound Cu 2 Cl 2 phen (phen = 1,10‐phenanthroline, C 12 H 8 N 2 ) 1 was synthesized from CuCl 2 ·2H 2 O, CuCl and phen by hydrothermal method and its structure was determined by single crystal X‐ray analysis. With phen, CuG forms one‐dimensional chains, which comprise two zigzag chains based on fused Cu‐X units and connected via covalent bonds. The compound contains two crystallographically unique monovalent copper ions, Cu(1) and Cu(2). The Cu(1) atom in the tetrahedral site, is coordinated to two bridging Cl − and two N atoms in phen. The Cu(2) atom with a slightly distorted triangular planar geometry, is coordinated to three Cl − . The compound 1 was crystallized in monoclinic, space group P2 1 / n with a = 0.37338(4), b = 1.9510(2), c = 1.68008(19) nm, β = 95.605 (3)°, R = 0.0458, and was characterized by elemental analysis, IR spectrum and TGA analysis.