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A Triple Cluster Platinaborane: [(P (2) Ph 3 )Pt (1) (μ 2 ‐B (11) ‐(B (9) ‐OC(CH 3 ) 3 ‐B 10 H 10 ))Pt (7) (P (1) Ph 3 )] 2
Author(s) -
Hu ChunHua,
Yong Wei,
Dou JianMin,
Sun Jie,
Hu KeJi,
Jin RuoShui,
Zheng PeiJu
Publication year - 2002
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20020200603
Subject(s) - chemistry , cluster (spacecraft) , crystallography , parallelogram , stereochemistry , physics , hinge , classical mechanics , computer science , programming language
The title platinaborane, [(P (2) Ph 3 )Pt (l) (μ 2 ‐B (11) ‐(B (9) ‐OC‐(CH 3 )3‐B 10 H 10 )Pt (7) (P (1) Ph 3 )] 2 , a triple cluster, which is a binuclear Pt complex dimmer, was prepared. Single crystal X‐ray diffraction analysis shows that a Pt (7) atom served as a common vertex between cluster |PtB 10 | and |Pt 4 |. The |Pt 4 | cluster is of parallelogram.