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Synthesis, Structure and Reactivity of Lanthanocene Complexes
Author(s) -
Qian ChangTao,
Zhu ChengJian
Publication year - 2002
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20020200602
Subject(s) - chemistry , intramolecular force , heteroatom , cyclopentadienyl complex , ring (chemistry) , reactivity (psychology) , stereochemistry , crystallography , organic chemistry , catalysis , medicine , alternative medicine , pathology
A variety of lanthanocene complexes, e. g . chlorides, hydrocarbyls, amides, hydrides and divalent derivatives, were synthesized by using a series of designed cyclopentadienyl, indenyl and fluorenyl ligands with ring bridges or donor‐functionalized sidearms. X‐Ray crystallographic analyses reveal the formation of intramolecular coordination bonds between central metals and heteroatoms (O, N) in sidearms or bridging chains. Some applications of these complexes are also discussed in this account.