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Recent Advances in Organic Reactions Catalyzed by Lanthanide (III) Complexes
Author(s) -
RuiFang Chen,
ChangTao Qian
Publication year - 2002
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20020200502
Subject(s) - chemistry , lanthanide , catalysis , organic synthesis , organic reaction , lewis acids and bases , combinatorial chemistry , organic chemistry , ion
Abstract Lanthanide compounds have been attracting much attention in organic synthesis. Chiral Ln‐substituted BINOL have been widely studied in several asymmetric organic reactions. LnCl 3 and Ln(OTf) 3 have been expected to serve as Lewis acids and have been applied to many important synthetic reactions in a one‐pot manner. Ln(O‐ i ‐Pr) 3 exhibits some basic characters, which also can be utilized in some special organic transformation. This article deals with some lanthanides(III) complexes promoted organic reactions, which we have recently developed.