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Synthesis and Characterization of β‐Cyclodextrin Bonded Metal Porphyrins
Author(s) -
Li ZaoYing,
Li Cong,
Li JiaFeng
Publication year - 2002
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20020200420
Subject(s) - chemistry , porphyrin , cyclodextrin , metal , elemental analysis , proton nmr , polymer chemistry , medicinal chemistry , inorganic chemistry , photochemistry , organic chemistry
Reactions of 5‐( p ‐aminophenyl)‐10,15,20‐triphenyl porphyrin (1) with Ru 3 (CO) 12 or M(OCOCH 3 ) 2 (M= Ni, Mn) afforded metalloporphyrins (4–6), respectively. 6‐Deoxy‐6‐iodo‐β‐cyclodextrin (2) and mono(6‐ O ‐trifluoromethanesulfonyl) permethylated β‐cyclodextrin (3) reacted with complexes 4–6 to give β‐cyclodextrin bonded metal porphyrins (7–9) and permethylated β‐cydodextrin bonded metal porphyrins (10–12) respectively. These new complexes were identified by MS, IR, UV‐visible and 1 H NMR spectra, and elemental analysis.