A Nitrilotriacetate Bridged Heteronuclear Co (II)‐Na (I) Polymer: {[CoNa (NTA) (H 2 O) 3 ] · 2H 2 O}  n | Zendy

Hu MaoLin | Zendy; Lin JuanJuan | Zendy; Miao Qian | Zendy; Xiong Yi | Zendy

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A Nitrilotriacetate Bridged Heteronuclear Co (II)‐Na (I) Polymer: {[CoNa (NTA) (H 2 O) 3 ] · 2H 2 O} n

Author(s) -

Hu MaoLin,

Lin JuanJuan,

Miao Qian,

Xiong Yi

Publication year - 2002

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.20020200306

Subject(s) - chemistry , heteronuclear molecule , orthorhombic crystal system , crystallography , electrochemistry , aqueous solution , cyclic voltammetry , ion , zigzag , cobalt , inorganic chemistry , stereochemistry , crystal structure , nuclear magnetic resonance spectroscopy , electrode , organic chemistry , geometry , mathematics

A novel Co (II) ‐ Na (I) heterometallic coordination polymer {[CoNa (NTA) (H 2 O) 3 ] · 2H 2 O} n (NTA = nitrilotriacetate) was synthesized and characterized by elemental analysis and X‐ray diffraction study. The electrochemical behavior in aqueous solution was measured by cyclic voltammetry, indicating a quasi‐reversible process. The complex crystallizes in the orthorhombic space group Pbca with the cell parameters a = 1.47276 (3) nm, b = 0.97280 (3) nm, c = 1.92946 (6) nm, V = 2.76434 (13) nm 3 , Z = 8. In the title complex, there are two kinds of zigzag chains which interconnect together to form 2D network. One stretches along the b ‐axis, comprising Co (II) ions, the other stretches along the c ‐axis, comprising Na (I) ions.

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