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Formation and Molecular Structure of an Ion Pair Iron (II) Compound Derived from 2,6‐Bis‐ [1‐(2,6‐dibromophenylimino) ‐ethyl] pyridine and 2‐Acetyl‐6‐[1‐(2, 6‐dibromophenylimino)‐ethyl] pyridine
Author(s) -
Chen RuiFang,
Qian ChangTao,
Sun Jie
Publication year - 2001
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20010190911
Subject(s) - chemistry , pyridine , monoclinic crystal system , crystal structure , ion , medicinal chemistry , crystallography , stereochemistry , organic chemistry
Two novel tridentate ligands of 2,6‐bis‐[l‐(2,6‐dibromophenylimino) ethyl] pyridine (L 1 ) and2‐acetyl‐6‐[1‐(2,6‐dibromophenylimino) ethyl] pyridine (L2) have been synthesized. The iron(II) complex of L 1 and L 2 has been characterized with the crystal structure of [Fe(L 1 )(L 2 )] 2+ [FeCl 4 ] 2 CH 2 Cl 2 [monoclinic, P2 1 (#11), a = 1.0562(4), b = 2.0928(4), c = 1.2914(2) nm, β = 100.12°, V = 2.810(1) nm 3 D c = 1.879 g/cm 3 and Z = 2].