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Structure of Bischloro tris (1, 10‐phenanthroline) copper (II) Dichloromethane Solvate Nonahydrate: [Cu(phen) 3 ]Cl 2 CH 2 Cl 2 ·9H 2 O
Author(s) -
Jian FangFang,
Lin JieHua,
Zhang ShuSheng
Publication year - 2001
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20010190811
Subject(s) - triclinic crystal system , chemistry , dichloromethane , hydrogen bond , copper , crystallography , octahedron , crystal structure , molecule , phenanthroline , chloride , ion , inorganic chemistry , organic chemistry , solvent
The crystal and molecular structures of [Cu(phen) 3 ] Cl 2 · CH 2 Cl 2 . 9H 2 O (PHEN= 1, 10‐pbenanthroline) have been determined by X‐ray crystallography. The complex crystallizes in triclinic system, space group P 1, with lattice parameters a = 1.26000(3), b = 1.37525(4), c = 1.42750(3)nm, α = 85.2970(1),β = 66.8400(1), γ= 83.09(1)°, and Z = 2. The coordinated cations contain a six‐coordinated copper atom chelated by three PHEN ligands, and the Jahn‐Teller effect of the Cu(II) ion results in a distorted octahedral arrangement with the six CuN distances ranging from 0.2112(6) to 0.2265(7) nm. In addition to the copper coordinated cation, there are two chloride ions, one dichloromethane solvate and nine water molecules in its asymmetric unit. In the solid state, the title compound forms three dimensional network structures through hydrogen bonds. The intermolecular hydrogen bonds connect the [Cu(phen) 3 ] 2+ , chloride ion, dichloromethane solvate and H 2 O moieties altogether.