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Reductive Cyclodimerization of α, β‐ Unsaturated Ketones Promoted by AlCl 3 /Sm System : A Facile Synthesis of 2‐Aroyl‐1,3,4‐triaryl Cyclopentanol Derivatives
Author(s) -
Fan XueSen,
Zhang YongMin
Publication year - 2001
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20010190614
Subject(s) - chemistry , regioselectivity , bimetallic strip , double bond , medicinal chemistry , reductive elimination , organic chemistry , catalysis
Promoted by AlCl 3 /Sm bimetallic system, α, β‐unsaturated ketones underwent reductive cyclodimerization to afford cyclopentanol derivatives under mild conditions. The reaction is stereocontrolled and regioselective over the competitive carbon‐carbon double bond reduction.