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A Convenient Synthesis and Molecular Structure of Ru(CO) 3 [Ph 2 PN( i ‐Bu)PPh 2 ‐P, P]
Author(s) -
Xu FengBo,
Zhang ZhengZhi
Publication year - 2001
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20010190518
Subject(s) - chemistry , crystal structure , trigonal bipyramidal molecular geometry , crystallography , x ray crystallography , stereochemistry , molecule , medicinal chemistry , diffraction , organic chemistry , physics , optics
Ru(CO) 3 [Ph 2 PN ( i ‐Bu) PPh 2 ‐P, P] was conveniently obtained by the reaction of Ru(DMSO) 4 Cl 2 with Ph 2 PN( i ‐Bu)‐PPb 2 and CO in the presence of Zn powder under mild conditions. The crystal and molecular structure was determined by X‐ray diffraction. This compound possesses a distorted trigonal bipyramidal configuration.