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Intermolecular Heterocoupling Reaction between N‐Sulfonylimines and Aliphatic Ketones Promoted by Samarium (II) Iodide
Author(s) -
Liu YunKui,
Zhang YongMin,
Liu Xi
Publication year - 2001
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20010190512
Subject(s) - chemistry , iodide , samarium , intermolecular force , samarium diiodide , organic chemistry , catalysis , ammonium iodide , medicinal chemistry , photochemistry , molecule
N ‐sulfonylimines (1) were induced by samarium(II) iodide to produce radical anion intermediates (2) in situ , which were trapped by aliphatic ketones (4) to afford heterocoupling products β‐sulfonamido alcohols (5) in moderate to good yields under mild and neutral conditions.