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Crystal Structure and Characterization of Pd(II) Bis(diiso‐propyldithiocarbamate) Complex
Author(s) -
Xu LiangZhong,
Zhao PuSu,
Zhang ShuSheng
Publication year - 2001
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20010190422
Subject(s) - chemistry , dithiocarbamate , crystal structure , crystallography , molecule , crystal (programming language) , ion , planar , stereochemistry , organic chemistry , computer science , programming language , computer graphics (images)
The crystal and molecular structure of [Pd( i Pr 2 dtc) 2 ] (dtc = dithiocarbamate) have been determined by X‐ray crystallography. The unit cell of the crystal structure consists of two discrete monomelic molecules of [Pd( i Pr 2 dtc) 2 ]. The Pd(II) ion has an square‐planar geometry. The electronic and IR spectral data are in agreement with the X‐ray structure. The TG data indicate slight degradation of a few percent.