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Molecular and Crystal Magnetic Engineering of Polymetallic Coupling System: From Magnetic Molecules to Molecular Magnets
Author(s) -
Cheng Peng,
Liao DaiZheng
Publication year - 2001
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20010190302
Subject(s) - molecular engineering , chemistry , magnetism , crystal engineering , magnet , ferromagnetism , molecular magnets , crystal (programming language) , coupling (piping) , nanotechnology , molecule , magnetic field , chemical physics , condensed matter physics , mechanical engineering , magnetization , materials science , organic chemistry , physics , engineering , quantum mechanics , computer science , programming language , hydrogen bond
One of the main challenges in the field of molecular materials is the design of molecular ferromagnets. General design strategy includes two steps, that is molecular magnetic engineering and crystal magnetic engineering. The first step is the synthesis of ferromagnetically coupled polymetallic systems. The second step is the assembly of polymetallic systems with muti‐dimensional structure and exhibiting a ferromagnetic transition. This paper summarized the strategies of molecular design and crystal engineering allowed to obtain such systems and our efforts in the fields of molecular magnetism and molecular‐based magnets.