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Synthesis and Disproportionation of Mixed Ligand Indium Organometallics Involving Ethyl and β‐Diketonate Chelate Lig‐ands
Author(s) -
Hu YiMin,
Huang XiaoHua,
Ye ZhongWen,
Wang XiuRan,
Gu JiaShan,
Sun Jie
Publication year - 2001
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20010190119
Subject(s) - chemistry , disproportionation , chelation , indium , ligand (biochemistry) , crystal structure , medicinal chemistry , stereochemistry , polymer chemistry , crystallography , organic chemistry , catalysis , biochemistry , receptor
Twelve compounds either of type Et 2 ln(diket) or Etln(diket) 2 (diket = β‐diketonate) have been synthesized, and all these compounds tend to disproportionate into Et 3 ln and ln(diket) 3 at moderately high temperature. Compounds of the latter type are much more thermally stable than those of the former. Moreover, ln(CH 3 COCHCOCH 3 ) 3 has been synthesized and its crystal structure has been determined.