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A facile route for the syntheses of trisilanes containing C ‐mono‐substituted carborane
Author(s) -
Luo YuMei,
Liu Fei,
Wu ShiHui
Publication year - 2000
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20000180618
Subject(s) - chemistry , chloroform , carborane , aluminium chloride , chloride , hydrogen chloride , catalysis , medicinal chemistry , organic chemistry , aluminium , hydrogen
The syntheses of trisilanes containing C ‐monosubstituted o ‐carborane are described. The intermediate compund 2‐chloro‐2‐phenyl‐hexamethylsilane was prepared by elimination reaction between 2, 2‐diphenylhexamethyltrisilane and hydrogen chloride with a catalytic amount of aluminium chloride in chloroform solution.