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Syntheses and molecular self‐assembly of chiral phosphoramidates
Author(s) -
Du DaMing,
Hua WenTing,
Wang JianWu,
Jin XiangLin
Publication year - 2000
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20000180520
Subject(s) - phosphoramidate , chemistry , hydrogen bond , molecule , intermolecular force , biphenyl , crystallography , stereochemistry , organic chemistry
Two chiral phosporamidates, ( R )‐(–)‐1, 1′‐binaphthyl‐2, 2′dihydroxy‐ N ‐ [α‐( S )‐methylbenzyl] phosphoramidate and (–)‐1,1′‐biphenyl‐2,2′‐dihydroxy‐ N‐ [α‐( S )‐methylbenzyl]‐phosphoramidate were synthesized. Their crystal structures were determined by X‐ray single crystal diffraction analysis. The phosphoramidate molecules are self‐associated by intermolecular NH ···O = P hydrogen bonds and aromatic edge to face interactions.