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Separation of chiral phosphorus compounds on the substituted β‐cyclodextrin stationary phase in normal‐phase liquid chromatography
Author(s) -
Hyi Chen,
XianYu Lu,
RuYu Gao,
Jia Zhou,
QinSun Wang
Publication year - 2000
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20000180414
Subject(s) - chemistry , enantiomer , cyclodextrin , carbamate , chromatography , phosphorus , phase (matter) , high performance liquid chromatography , chiral derivatizing agent , derivative (finance) , chiral column chromatography , chiral stationary phase , organic chemistry , financial economics , economics
The separation of enantiomers of a series of eighteen novel nitrogen mustard linked phosphoryl diamide derivatives was investigated on the prepared phenyl carbamate derivative β‐cyclodextrin bonded phase in normal‐phase HPLC. Some of the enantiomers could be separated in baseline. The chiral recognition mechanism was also suggested for the separation of chiral phosphorus organic compounds.