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A new class of chiral pyrrolidine ligands for homogeneous catalytic enantioselective cyclopropanation of styrene
Author(s) -
Min Shi,
JianKang Jiang
Publication year - 2000
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20000180327
Subject(s) - cyclopropanation , enantioselective synthesis , pyrrolidine , chemistry , styrene , homogeneous , enantiomer , catalysis , asymmetric induction , organic chemistry , copolymer , polymer , physics , thermodynamics
A new class of chiral pyrrolidine ligands have been successfully synthesized and their chiral induction abilities have been examined in the homogeneous catalytic enantioselective cyclopropanation of styrene. 15–30% enantiomeric excess ( ee ) has been achieved.