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Bis‐perfluoroalkylation of aromatic compounds with sodium perfluoroalkanesulfinates
Author(s) -
JinTao Liu,
HeJun Lu
Publication year - 2000
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20000180326
Subject(s) - chemistry , anisole , quinoline , pyridine , sodium , medicinal chemistry , organic chemistry , catalysis
Bis‐perfluoroalkylation of aromatic compounds such as dimethoxybenzenes (2, 4, 6), anisole (8), pyridine (10) and quinoline (13) was accomplished by reaction with excess sodium perfluoroalkanesulfinates, R F SO 2 Na (1), in the presence of Mn(OAc) 3 ·2H 2 O under mild conditions. The reaction provides a facile method for the synthesis of bis‐perfluoroalkylated aromatic compounds.
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