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Fructose derived pyridyl alcohol ligands: Synthesis and application in the asymmetric diethylzinc addition to aldehydes
Author(s) -
YongGui Zhou,
LiXin Dai,
XueLong Hou
Publication year - 2000
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.20000180122
Subject(s) - diethylzinc , chemistry , alcohol , fructose , organic chemistry , optically active , enantioselective synthesis , combinatorial chemistry , catalysis
Easily available chiral ketones were employed for the synthesis of optically active pyridyl alcohols, which were applied in the asymmetric diethylzinc addition to aldehydes, up to 89.4% e.e . was obtained using D ‐fructose‐derived pyridyl alcohol.
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