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Samarium mediated pinacol coupling of carbonyl compounds in the presence of a catalytic amount of iodine under aqueous media
Author(s) -
Wang Lei,
Zhang YongMin
Publication year - 1999
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.19990170518
Subject(s) - chemistry , pinacol , iodine , catalysis , aqueous medium , aqueous solution , samarium , coupling (piping) , photochemistry , organic chemistry , metallurgy , materials science
In the presence of a catalytic amount of iodine, metallic samarium mediated pinacol coupling of carbonyl compounds has been carried out under saturated aqueous Nl&Cl‐THF conditions at mom temperature. It gives corresponding 1,2‐diols in god yields.