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Asymmetric allylation of aldehydes and alkylation using “carbon‐centered” chiral organosilicon compounds
Author(s) -
Wang Dong
Publication year - 1999
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.19990170502
Subject(s) - organosilicon , chemistry , silicon , stereoselectivity , alkylation , asymmetric carbon , atom (system on chip) , carbon atom , chiral auxiliary , carbon fibers , organic chemistry , computational chemistry , enantioselective synthesis , medicinal chemistry , catalysis , optically active , alkyl , computer science , materials science , composite number , composite material , embedded system
The effects of the chiral substituents attached to silicon on the stereoselectivity of the reactions of C‐centered chiral silicon compounds wm examined. The investigation was focused on the asymmetric C—C bond formation reaction of chiral allylsilanes and α‐silylallyl anions with aldehydes. The functionalities of the substituents on silicon can be manipulated to improve the stereoselectivities of the reactions remote from silicon atom.