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Coupling matrix element of electron self‐exchange reactions in solution
Author(s) -
YuXiang Bu,
ChengBu Liu,
CongHao Deng
Publication year - 1998
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.19980160604
Subject(s) - chemistry , matrix (chemical analysis) , electron transfer , coupling (piping) , matrix element , ion , electron , coupling reaction , chemical physics , computational chemistry , atomic physics , molecular physics , quantum mechanics , physics , organic chemistry , composite material , materials science , chromatography , particle physics , catalysis
On the basis of the common feature among the electron transfer process and the ion hydration process as well as the relevant experimental kinetic data of electron trader reaction, a new accurate hydration potential function scheme for the determination of electron transfer coupling matrix element is presented. The coupling matrix element between two hydrated ions of the reacting system in solution is calculated. The results and the applicability of this scheme are discussed.