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Standard Gibbs energies of transfer of rubidium tetraphenylborate from water to straight‐chain n ‐alkanols
Author(s) -
LiZhuang Zou,
XiaoLing Wang,
FengGe Wang,
PiJian Zhang,
XiangKun Guo,
BaoXue Zhou,
SongSheng Qu
Publication year - 1998
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.19980160403
Subject(s) - chemistry , tetraphenylborate , gibbs free energy , rubidium , thermodynamics , analytical chemistry (journal) , organic chemistry , potassium , ion , physics
Abstract Solubilities of ribidium tetraphenylborate in water, methanol, ethanol, 1‐propanol, 1‐butanol, 1‐pentanol, 1‐hexanol and l‐octanol at 288.15, 298.15, 308.15, 318.15, 328.15 K have been determined by spectrophotometry. The standard Gibbs energy of transfer of ribidium tetraphenylborate from water to straight‐chain n ‐alkanols and the primary medium effect of rubidium tetraphenylborate from 288.15 to 328.15 K have been calculated. Furthermore, the contribution of microscopic interactions to the standard Gibbs energy of transfer of rubidium tetraphenylborate in calculated and discussed.