NMR study on solubility of benzyl alcohol and its transfer free energy from D 2 O to cationic micelle | Zendy

Shen Qiang | Zendy; Li GanZuo | Zendy; Ma ChengSong | Zendy; Hao ShuXuan | Zendy; Wei XiLian | Zendy; Huang YanZhang | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

NMR study on solubility of benzyl alcohol and its transfer free energy from D 2 O to cationic micelle

Author(s) -

Shen Qiang,

Li GanZuo,

Ma ChengSong,

Hao ShuXuan,

Wei XiLian,

Huang YanZhang

Publication year - 1997

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.19970150504

Subject(s) - chemistry , solubility , benzyl alcohol , micelle , alcohol , cationic polymerization , aqueous solution , pulmonary surfactant , micellar solutions , phase (matter) , medicinal chemistry , organic chemistry , catalysis , biochemistry

A new kind of surfactant, [C n H 2 n +1 OCH 2 CH(OH)CH 2 N(CH 3 ) 3 ]Cl ( n =12, 14, 16) was synthesized. The solubility of benzyl alcohol in micellar solutions was determined by 1 H NMR method. The results indicate that the length of alkyl chains of surfactant affects the solubility of benzyl alcohol in 2.5 × 10 −2 mol/L micellar solutions. The solubility of benzyl alcohol per liter of micellar solution is 0.095 mole for n =12, 0.115 mole for n =14, 0.165 mole for n =16. The transfer free energy of benzyl alcohol from aqueous phase to micellar phase is −24.29 kJ/mol for n =12, −24.37 kJ/mol for n =14, −24.49 kJ/mol for n =16.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research