Hypersensitivity and its application to structural analysis of lanthanide complexes | Zendy

Yang Wu | Zendy; Chen Miao | Zendy; Gao JinZhang | Zendy; Yang WeiDong | Zendy; Kang JingWan | Zendy; Yang HongWu | Zendy

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Hypersensitivity and its application to structural analysis of lanthanide complexes

Author(s) -

Yang Wu,

Chen Miao,

Gao JinZhang,

Yang WeiDong,

Kang JingWan,

Yang HongWu

Publication year - 1997

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.19970150110

Subject(s) - chemistry , square antiprism , lanthanide , ternary operation , holmium , neodymium , symmetry (geometry) , erbium , crystallography , acetone , inorganic chemistry , ion , laser , organic chemistry , doping , condensed matter physics , physics , geometry , mathematics , computer science , optics , programming language

Hypersensitivity of the ternary complexes Ln(β‐dik) 4 HMQ(where Ln=Nd, Ho, Er, β‐dik=acetylacetonate(AA), dibenzoylmethanate(DBM) and MQ=4‐methylquinoline) in acetone solution is studied based on the dynamic coupling model. The structures of these complexes in solution are deduced. Their coordination polyhydrons are all distorted square antiprism. Neodymium complexes have D 2 symmetry, while holmium and erbium complexes have exact D 2d symmetry.

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