Isomeric structures, isomerization and decomposition of silylenoids H 2 SiMX (MXKF, KCl, LiBr, NaBr and KBr) | Zendy

Feng DaCheng | Zendy; Feng ShengYu | Zendy; Deng CongHao | Zendy

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Isomeric structures, isomerization and decomposition of silylenoids H 2 SiMX (MXKF, KCl, LiBr, NaBr and KBr)

Author(s) -

Feng DaCheng,

Feng ShengYu,

Deng CongHao

Publication year - 1995

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.19950130602

Subject(s) - chemistry , isomerization , decomposition , ring (chemistry) , dissociation (chemistry) , ab initio , tetrahedron , computational chemistry , crystallography , organic chemistry , catalysis

The isomeric structures, isomerization and decomposition of silylenoids H 2 SiMX (MXKF, KC1, LiBr, NaBr and KBr) have been investigated by ab initio molecular orbital theory. These silylenoids have four kinds of very similar equilibrium structures. The three‐membered ring and p ‐complex structures should be stable and experimentally detectable. The lifetime of σ‐complex and tetrahedral structures would be very short and experimentally undetectable.

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