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Addition of polyfluoropolyhaloethanes to alkenes
Author(s) -
Chen Jian,
Hu ChangMing
Publication year - 1995
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.19950130313
Subject(s) - chemistry , moiety , adduct , redox , combinatorial chemistry , medicinal chemistry , organic chemistry
In the presence of CrCl 3 /Fe redox system, polyfluoropolyhaloethanog readily added to electron‐deficient or electron‐rich alkenes, giving the corresponding 1:1 hydropolyfluoroalkylation product or 1:1 adduct in high yields. This reaction provided a simple and convenient method to synthesize building blocks containing a CF 3 or CF 2 moiety.