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Nonadiabatic collision model calculations of ion‐pair formation cross sections of Cs+O 2 →Cs + +O 2 −
Author(s) -
Cai ZhengTing,
Mu YuGuang,
CongHao Den G.
Publication year - 1995
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.19950130302
Subject(s) - chemistry , collision , ion , atomic physics , trajectory , line (geometry) , quantum mechanics , physics , geometry , computer security , mathematics , organic chemistry , computer science
This paper has improved Hickman's nonadiabatic collision model by substituting Hickman's constant velocity classical straight line trajectory approximation with the solution of motion equation mR =−d V(R )/dR, and has calculated the cross sections of ion‐pair formation Cs+O 2 →Cs + +O − 2 with the improved nonadiabatic collision model (INCM). A comparison of our results with other theoretical and experimental results has been made.