Premium
Direct fabrication of conductive LB films composed of N ‐docosylpyridinium‐TCNQ
Author(s) -
Yuan ChunWei,
Wu HaiMing,
Xiao Dong,
Wei Yu
Publication year - 1994
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.19940120203
Subject(s) - chemistry , x ray photoelectron spectroscopy , valence (chemistry) , conductivity , absorption spectroscopy , molecule , absorption (acoustics) , fabrication , analytical chemistry (journal) , crystallography , chemical engineering , organic chemistry , optics , materials science , composite material , physics , engineering , medicine , alternative medicine , pathology
Langmuir‐Blodgett (LB) films of Ar‐docosylpyridinium‐TCNQ (NDP‐TCNQ) were prepared in air. The films deposited at the room temperature showed in‐plane conductivity of 4·10 −3 S·cm −1 and its absorption spectra in UV and IR regions resembled those for the films composed of mixed‐valence TCNQ salts of NDP‐(TCNQ) 2 rather than for the NDP‐TCNQ LB films preparaed under protection of nitrogen. In the case that the films left in a warm environment after each dipping cycle, the absorption in the corresponding region changed. Spectral analysis and XPS study revealed that more TCNQ molecules were produced. The oxidation of TCNQ: in air was considered to be the origin of neutral TCNQ formed.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom