Perfluoroalkylation of aromatics | Zendy

Huang WeiYuan | Zendy; Ying WeiWen | Zendy; Zhang HanZhong | Zendy; Liu JinTao | Zendy

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Perfluoroalkylation of aromatics

Author(s) -

Huang WeiYuan,

Ying WeiWen,

Zhang HanZhong,

Liu JinTao

Publication year - 1993

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.19930110313

Subject(s) - chemistry , sodium dithionite , reagent , bromide , trifluoromethylation , iodide , sodium iodide , organic chemistry , solvent , salt (chemistry) , sodium bromide , sodium , alkyl , trifluoromethyl

Several methods for the perfluoroalkylation of aromatics were reported. Both perfluoroalkanesulfonyl bromide/BPO and perfluoroalkanesulfinate/oxidant, systems were efficient reagents for the introduction of a perfluoroalkyl group onto various aromatic nuclei. In a two‐phase solvent system with tetraalkylammonium salt as PTC, reaction of perfluoroalkyl iodide and aromatics in the presence of sodium dithionite gave perfluoroalkyl aromatics and/or addition‐dimerization products.

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