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Studies on sulfinatodehalogenation. XXVIII. The addition of polyfluoroalkyl iodides to olefins initiated by sodium disulfite
Author(s) -
Huang BingNan,
Wu FanHong
Publication year - 1993
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.19930110214
Subject(s) - chemistry , adduct , sodium , aqueous solution , sodium salt , radical , sodium iodide , medicinal chemistry , organic chemistry , inorganic chemistry
Polyfluoroalkyl iodides reacted with olefins in aqueous DMF solution of sodium disulfite under mild conditions to give the corresponding 1:1 adducts in good yields, providing a convenient polyfluoroalkylation method. This indicated that R F . radicals were formed in the reaction of polyfluoroalkyl iodides and sodium disulfite. A SET mechanism is proposed for the sulfinatodehalogenation reaction of sodium disulfite.