Studies on sulfinatodehalogenation. XXVIII. The addition of polyfluoroalkyl iodides to olefins initiated by sodium disulfite | Zendy

Huang BingNan | Zendy; Wu FanHong | Zendy

Premium

Studies on sulfinatodehalogenation. XXVIII. The addition of polyfluoroalkyl iodides to olefins initiated by sodium disulfite

Author(s) -

Huang BingNan,

Wu FanHong

Publication year - 1993

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.19930110214

Subject(s) - chemistry , adduct , sodium , aqueous solution , sodium salt , radical , sodium iodide , medicinal chemistry , organic chemistry , inorganic chemistry

Polyfluoroalkyl iodides reacted with olefins in aqueous DMF solution of sodium disulfite under mild conditions to give the corresponding 1:1 adducts in good yields, providing a convenient polyfluoroalkylation method. This indicated that R F . radicals were formed in the reaction of polyfluoroalkyl iodides and sodium disulfite. A SET mechanism is proposed for the sulfinatodehalogenation reaction of sodium disulfite.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research